MTBE Has Been Detected in Surface Public Drinking Water Sources
in California
Where are these sources located?
Geography 26 - GIS Data Acquisition Class
Spring Semester 2000
American River College
Sacramento, California
Brian Levers
Abstract
The gasoline oxygenate methyl-tertiary butyl ether (MTBE) has
been found in California ground and surface public drinking water sources.
These public sources are monitored by the State
of California Department of Health Services (DHS). This paper deals
only with surface public drinking water sources containing
MTBE as reported by the DHS. Since some of these source names are not well
known across the state, and in some cases their locations are far removed
geographically from the communities served, the author felt it would be
helpful to enhance the DHS's tabular data by adding location maps, and,
if available, other information such as photos, etc.
Introduction
Concern about drinking water ground and surface source contamination
by the toxic gasoline oxygenate methyl-tertiary butyl ether (MTBE) has
fueled heated public debate about the health risks posed and the potentially
astronomical costs to remove it from contaminated water sources.
It has been added in relatively low concentrations to increase octane ratings
in gasoline since the mid-1970's. Beginning in the early 1990's MTBE
has been added in much higher concentrations (up to 15 percent) to enhance
gasoline combustion and reduce tailpipe emissions. This paper focuses
only on surface public drinking water sources monitored by
the State of California's Department of Health Services (DHS).
It is important to note that thousands of California bays, lakes, reservoirs,
ponds, creeks, streams, and wetlands are not monitored by DHS because they
are not considered surface public drinking water sources,
these may or may not have MTBE contamination. Although tests for
MTBE have been done on many of these non-DHS-monitored water bodies, the
data is not available from DHS and is beyond the scope of this paper. For
a public (ground or surface) drinking water source to be considered
by DHS as being positive for MTBE, the DHS requires at least two MTBE-positive
samples from the same source. Although DHS requires that water agencies
report only MTBE contamination levels at or greater than the "Detection
Limit for Reporting" (DCL) of 3.0 micrograms per Liter, some agencies
turn in all positive test results. This paper is based on a
DHS-published table which lists: surface public drinking water source names
where MTBE has been reported as detected (at any level) in at least two
samples; number of MTBE-positive samples taken; date range over which samples
were taken; and range of detected MTBE levels in micrograms per liter (ug/L).
[note: 3.0 ug/L (micrograms/Liter) = 0.003 mg/L (milligrams/Liter) = 3.0
ppb (parts-per-billion)]. Building upon the information provided in the
DHS table, the author has added links to locator maps plus public water
agency information and photos (if available).
Background
MTBE has been detected in a number of groundwater and surface water
sources and is considered a possible human carcinogen. It is highly soluble
in water, does not readily degrade in the environment, and most public
water systems are not equipped to completely remove it from drinking water.
MTBE is often described as having a turpentine-like taste and smell, even
at very low concentrations. Initial studies show that some consumers can
detect it in drinking water at concentrations as low as 2.5 micrograms
per liter (ug/L). With such a low taste and odor threshold, many
experts believe consumers would notice MTBE contamination at much lower
levels than are likely to cause health effects.
California wine growers are concerned
that an otherwise superb product reputation could be tarnished by minute
levels of MTBE contamination.
In order to measure the presence of MTBE in California drinking water
supplies the DHS in February 1997 required public water utilities to begin
testing their sources of drinking water for MTBE. Although
this paper focuses only on surface public drinking water
sources monitored by the DHS, it is worth noting that the problem of ground
water MTBE contamination appears to pose a greater threat than surface
water contamination, and is also monitored by the DHS. For example, the
City
of Santa Monica in 1996 had to shut down the majority of the City's
drinking water wells due to MTBE contamination. South
Tahoe Public Utility District has been forced to close at least 13
of its 34 drinking water wells due to MTBE contamination or the threat
of contamination. As a result of MTBE contamination, public drinking water
wells have been closed down in Santa Clara County, the City of Sacramento,
and the towns of Glennville, Riverview, and Cambria. Some water districts
have imposed restrictions on motorized recreation at surface water reservoirs
to reduce the release of MTBE from two-stroke marine engines, but two-stroke
marine engines are not the only source of MTBE surface source contamination.
Lakes and reservoirs where no gasoline-powered boats are allowed have been
found to contain MTBE. In addition to two-stroke marine engines as a source
of contamination, MTBE-laden fuel spilled at gasoline stations is eventually
washed into storm drains, and then on to creeks, streams, rivers, lakes
and reservoirs. Due to its extremely high water solubility,
MTBE, whether from engine exhaust or evaporation, combines with water vapor
and rises up into the atmosphere, eventually falling back to earth with
precipitation, often many miles distant from where it originated, even
upon isolated pristine mountain lakes and ponds.
Methods
After doing a search on the internet for information on MTBE contamination,
the best source of data within the scope of this project was found to be
California Department of Health Services' (DHS) website. DHS provides summary
tables of ground and surface drinking water sources in which MTBE has been
detected in two or more samples taken from the same source. Because the
exact locations (latitude/longitude) of water wells is not provided by
the DHS website, it was decided to focus only on surface sources. It was
hoped that these sources (in most cases lakes or reservoirs) could be easily
located by name and mapped using Arc View GIS. A problem became immediately
apparent. Some of the source names used in the DHS table either could not
be found in the Arc View dbf table of names, or multiple candidates with
similar names were found. To clarify the situation, an internet search
was done to find the websites for each public water agency listed in the
DHS table. Each agency's site was then visited to search for information
to determine the name and location of the most likely source name matching
the one cited in the DHS table. If available, service area maps and photographs
of these were downloaded. In the beginning stages of the project the author
found the software program Street Atlas 7.0 helpful in finding where some
of the more obscure sources were located. Once a likely geographic location
and its proximity to other water bodies nearby was determined, that area
was zoomed-in-to on the ArcView map, and, if a water body was found that
matched, Arc View's "Identify" tool was used to determine the Arc View
.dbf name.
Results
The DHS currently reports that out of 455 surface public drinking water
sources sampled in California for MTBE, 21 (4.6%) have had two or more
positive test samples. The author was able to show locations for
all except three surface sources listed in the DHS table. Given more
time, these would have been located. The table below was downloaded
from the DHS
website and source location information was added by the author using
a combination of author-created Arc View GIS maps and material downloaded
from other online sources.
(not included)
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